Grubbs' catalyst in paraffin: an air-stable preparation for alkene metathesis.
نویسندگان
چکیده
A homogeneous mixture of Grubbs' catalyst in paraffin wax was shown to catalyze three important types of metathesis reactions: ring-closing metathesis, alkene dimerization, and alkene cross-metathesis (e.g., 11 --> 13). This catalyst preparation demonstrated no loss in catalytic activity after 22 months of storage open to the air.
منابع مشابه
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 68 15 شماره
صفحات -
تاریخ انتشار 2003